Understanding how rechargeable aqueous zinc batteries work

Researchers have hoped that rechargeable zinc-manganese dioxide batteries — which promise safety, low cost and environmental sustainability — could be developed into a viable option for grid storage applications. Engineers at the University of Illinois Chicago and colleagues identified the atomistic mechanism of charge and discharge in such batteries.

UIC engineer Reza Shahbazian-Yassar with the ARM microscope. Photo: Jim Young/UIC College of Engineering

The researchers reached this conclusion after leveraging advanced electron microscopy, electrochemical experiments and theoretical calculations to look closer at how the zinc anode works with the manganese cathode in the battery system.

"Zinc and manganese separately have very favorable properties for high-quality sustainable batteries; however, when paired in a full system their intercalation — their rechargeability — has been debatable, with some recent studies suggesting zinc insertion and deinsertion in manganese dioxide is responsible for the rechargeability of the cells," said study lead author Reza Shahbazian-Yassar of UIC.

"With this study, we showed there is actually no microscopic evidence of zinc reinsertion into manganese dioxide, and what was previously thought to be indicators of recharging was from positively charged hydrogen ions being inserted in the manganese, not zinc."

In their experiments, the researchers built aqueous zinc-manganese dioxide cells and tested them over 100 cycles. They discharged and attempted to recharge the batteries in experiments while using electron microscopy to capture atomic-level images of the reactions.

"We saw that the hydrogen is responsible for the damage to the tunnel structures of manganese dioxide, further reducing the potential of the battery for recharging," Shahbazian-Yassar said.

"The information we've obtained with these experiments reveals important atomic insights into the mechanisms of the zinc-manganese battery. Now that we know what is happening at the cell level, we have a compass for finding better strategies."

Shahbazian-Yassar said different cell structures could make the system more favorable for zinc insertion or maybe strategies to harness the hydrogen protons. (U.S. National Science Foundation)

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