News / Science News

    Solar-powered system converts plastic and greenhouse gases into sustainable fuels

    The researchers, from the University of Cambridge, developed the system, which can convert two waste streams into two chemical products at the same time – the first time this has been achieved in a solar-powered reactor.



    Plastic bottles were converted into glycolic acid, which is widely used in the cosmetics industry. Photo: tanvi sharma/Unsplash


    The reactor converts carbon dioxide (CO2) and plastics into different products that are useful in a range of industries. In tests, CO2 was converted into syngas, a key building block for sustainable liquid fuels, and plastic bottles were converted into glycolic acid, which is widely used in the cosmetics industry.

    The system can easily be tuned to produce different products by changing the type of catalyst used in the reactor.

    Converting plastics and greenhouse gases – two of the biggest threats facing the natural world – into useful and valuable products using solar energy is an important step in the transition to a more sustainable, circular economy.

    “Converting waste into something useful using solar energy is a major goal of our research,” said Professor Erwin Reisner from the Yusuf Hamied Department of Chemistry, the paper’s senior author.

    “Plastic pollution is a huge problem worldwide, and often, many of the plastics we throw into recycling bins are incinerated or end up in landfill.”

    “A solar-driven technology that could help to address plastic pollution and greenhouse gases at the same time could be a game-changer in the development of a circular economy,” said Subhajit Bhattacharjee, the paper’s co-first author.

    “We also need something that’s tuneable, so that you can easily make changes depending on the final product you want,” said co-first author Dr Motiar Rahaman.

    The researchers developed an integrated reactor with two separate compartments: one for plastic, and one for greenhouse gases. The reactor uses a light absorber based on perovskite – a promising alternative to silicon for next-generation solar cells.

    The team designed different catalysts, which were integrated into the light absorber. By changing the catalyst, the researchers could then change the end product.

    Tests of the reactor under normal temperature and pressure conditions showed that the reactor could efficiently convert PET plastic bottles and CO2 into different carbon-based fuels such as CO, syngas or formate, in addition to glycolic acid.

    The Cambridge-developed reactor produced these products at a rate that is also much higher than conventional photocatalytic CO2 reduction processes.

    “Generally, CO2 conversion requires a lot of energy, but with our system, basically you just shine a light at it, and it starts converting harmful products into something useful and sustainable,” said Rahaman.

    “Prior to this system, we didn’t have anything that could make high-value products selectively and efficiently.” (University of Cambridge)

    JANUARY 31, 2023



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